A Semiconductor is a substance which has resistivity in between conductor and insulator .Copper is a good conductor which is resistivity is 1.7*10^-8.Germanium is a semiconductor which is reistivity is 0.6 ohm meter.A Glass is a good insulator which is resistivity is 9*10^ ohm meter.A Nichrome is a resistance material which is resistivity is 10^-4 ohm meter.
Comparing the resistivity of above materials it is apparent that resistivity of germanium is quite high as compared to copper but is quite low when compared with glass.This is shows that resistivity of a semiconductor lies in between conductors and insulators.
Types of semiconductors :
The semiconductors are classifieds as followed
(i) intrinsic semiconductors
(ii)Extrinsic semiconductors
In every elements,the atoms are tied together by the bonding action of valence electrons.Si and Ge atoms contains only 4 valence electrons.These electrons have tendency to fill the outer most orbit.In this way the electrons placed to in the last orbit of an atom share the electrons with their neighbor atoms. Similarly all the electrons are tied together with their neighboring atoms.
(i)Intrinsic Semiconductors :
A pure semiconductor is called intrinsic semiconductor.The silicon and Ge atoms contain only four electrons in the outermost orbit.So they are called tetravalent bonds.In an intrinsic semiconductors even at room temperature hole pair are created.
When electric field is applied across an intrinsic semiconductor ,the current conduction takes same place by two process which is free electrons and holes.Now no electrons get away from the co-valent bonds.So current flows is zero.